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Reversible coordination of N(2) and H(2) to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state
The synthesis and characterisation of the S = 1/2 Fe(i) complex [Fe(depe)(2)](+)[BArF4](–) ([1](+)[BArF4](–)), and the facile reversible binding of N(2) and H(2) in both solution and the solid state to form the adducts [1·N(2)](+) and [1·H(2)](+), are reported. Coordination of N(2) in THF is thermod...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6237127/ https://www.ncbi.nlm.nih.gov/pubmed/30542539 http://dx.doi.org/10.1039/c8sc01841c |