Reversible coordination of N(2) and H(2) to a homoleptic S = 1/2 Fe(i) diphosphine complex in solution and the solid state

The synthesis and characterisation of the S = 1/2 Fe(i) complex [Fe(depe)(2)](+)[BArF4](–) ([1](+)[BArF4](–)), and the facile reversible binding of N(2) and H(2) in both solution and the solid state to form the adducts [1·N(2)](+) and [1·H(2)](+), are reported. Coordination of N(2) in THF is thermod...

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Detalles Bibliográficos
Autores principales: Doyle, Laurence R., Scott, Daniel J., Hill, Peter J., Fraser, Duncan A. X., Myers, William K., White, Andrew J. P., Green, Jennifer C., Ashley, Andrew E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6237127/
https://www.ncbi.nlm.nih.gov/pubmed/30542539
http://dx.doi.org/10.1039/c8sc01841c

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