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Synthesis and reactivity of a PC(carbene)P cobalt(i) complex: the missing link in the cobalt PXP pincer series (X = B, C, N)
We report the first example of a cobalt PC(carbene)P pincer complex (1) featuring a central alkylidene carbon donor accessed through the dehydration of an alcoholic POP proligand. Complex 1 shares bonding similarities with cobalt PBP and PNP pincer complexes where the donor atom engages in π-bonding...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6240806/ https://www.ncbi.nlm.nih.gov/pubmed/30542572 http://dx.doi.org/10.1039/c8sc02782j |