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Gating the electron transfer at a monocopper centre through the supramolecular coordination of water molecules within a protein chamber mimic
Functionality of enzymes is strongly related to water dynamic processes. The control of the redox potential for metallo-enzymes is intimately linked to the mediation of water molecules in the first and second coordination spheres. Here, we report a unique example of supramolecular control of the red...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6240898/ https://www.ncbi.nlm.nih.gov/pubmed/30542577 http://dx.doi.org/10.1039/c8sc03124j |