Gating the electron transfer at a monocopper centre through the supramolecular coordination of water molecules within a protein chamber mimic

Functionality of enzymes is strongly related to water dynamic processes. The control of the redox potential for metallo-enzymes is intimately linked to the mediation of water molecules in the first and second coordination spheres. Here, we report a unique example of supramolecular control of the red...

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Detalles Bibliográficos
Autores principales: Le Poul, Nicolas, Colasson, Benoit, Thiabaud, Grégory, Dit Fouque, Dany Jeanne, Iacobucci, Claudio, Memboeuf, Antony, Douziech, Bénédicte, Řezáč, Jan, Prangé, Thierry, de la Lande, Aurélien, Reinaud, Olivia, Le Mest, Yves
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6240898/
https://www.ncbi.nlm.nih.gov/pubmed/30542577
http://dx.doi.org/10.1039/c8sc03124j

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