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A bench stable formal Cu(iii) N-heterocyclic carbene accessible from simple copper(ii) acetate

For years, Cu(iii)NHCs have been proposed as active intermediates in Cu(i)NHC catalyzed reactions, yielding the desired products by reductive elimination, but until today, no one has ever reported the characterisation of such a compound. When working on the synthesis of biomimetic transition metal (...

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Detalles Bibliográficos
Autores principales: Ghavami, Zohreh S., Anneser, Markus R., Kaiser, Felix, Altmann, Philipp J., Hofmann, Benjamin J., Schlagintweit, Jonas F., Grivani, Gholamhossein, Kühn, Fritz E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6240905/
https://www.ncbi.nlm.nih.gov/pubmed/30542579
http://dx.doi.org/10.1039/c8sc01834k