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A bench stable formal Cu(iii) N-heterocyclic carbene accessible from simple copper(ii) acetate
For years, Cu(iii)NHCs have been proposed as active intermediates in Cu(i)NHC catalyzed reactions, yielding the desired products by reductive elimination, but until today, no one has ever reported the characterisation of such a compound. When working on the synthesis of biomimetic transition metal (...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6240905/ https://www.ncbi.nlm.nih.gov/pubmed/30542579 http://dx.doi.org/10.1039/c8sc01834k |