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Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow

A copper-based photocatalyst, Cu(tmp)(BINAP)BF(4), was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and...

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Detalles Bibliográficos
Autores principales: Minozzi, Clémentine, Grenier-Petel, Jean-Christophe, Parisien-Collette, Shawn, Collins, Shawn K
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6244115/
https://www.ncbi.nlm.nih.gov/pubmed/30498523
http://dx.doi.org/10.3762/bjoc.14.251