Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow

A copper-based photocatalyst, Cu(tmp)(BINAP)BF(4), was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and...

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Autores principales: Minozzi, Clémentine, Grenier-Petel, Jean-Christophe, Parisien-Collette, Shawn, Collins, Shawn K
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6244115/
https://www.ncbi.nlm.nih.gov/pubmed/30498523
http://dx.doi.org/10.3762/bjoc.14.251
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author Minozzi, Clémentine
Grenier-Petel, Jean-Christophe
Parisien-Collette, Shawn
Collins, Shawn K
author_facet Minozzi, Clémentine
Grenier-Petel, Jean-Christophe
Parisien-Collette, Shawn
Collins, Shawn K
author_sort Minozzi, Clémentine
collection PubMed
description A copper-based photocatalyst, Cu(tmp)(BINAP)BF(4), was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and carboxylic acids to their anhydrides. The protocol was also amendable and optimized under continuous flow conditions.
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spelling pubmed-62441152018-11-29 Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow Minozzi, Clémentine Grenier-Petel, Jean-Christophe Parisien-Collette, Shawn Collins, Shawn K Beilstein J Org Chem Letter A copper-based photocatalyst, Cu(tmp)(BINAP)BF(4), was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and carboxylic acids to their anhydrides. The protocol was also amendable and optimized under continuous flow conditions. Beilstein-Institut 2018-10-30 /pmc/articles/PMC6244115/ /pubmed/30498523 http://dx.doi.org/10.3762/bjoc.14.251 Text en Copyright © 2018, Minozzi et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Minozzi, Clémentine
Grenier-Petel, Jean-Christophe
Parisien-Collette, Shawn
Collins, Shawn K
Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
title Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
title_full Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
title_fullStr Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
title_full_unstemmed Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
title_short Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
title_sort photocatalyic appel reaction enabled by copper-based complexes in continuous flow
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6244115/
https://www.ncbi.nlm.nih.gov/pubmed/30498523
http://dx.doi.org/10.3762/bjoc.14.251
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AT parisiencolletteshawn photocatalyicappelreactionenabledbycopperbasedcomplexesincontinuousflow
AT collinsshawnk photocatalyicappelreactionenabledbycopperbasedcomplexesincontinuousflow

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