Regio- and chemoselective Csp(3)–H arylation of benzylamines by single electron transfer/hydrogen atom transfer synergistic catalysis

We present a highly regio- and chemoselective Csp(3)–H arylation of benzylamines mediated by synergy of single electron transfer (SET) and hydrogen atom transfer (HAT) catalysis. Under well precedented SET catalysis alone, the arylation reaction of N,N-dimethylbenzylamine proceeded via aminium radic...

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Detalles Bibliográficos
Autores principales: Ide, Takafumi, Barham, Joshua P., Fujita, Masashi, Kawato, Yuji, Egami, Hiromichi, Hamashima, Yoshitaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6244453/
https://www.ncbi.nlm.nih.gov/pubmed/30542595
http://dx.doi.org/10.1039/c8sc02965b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6244453/
https://www.ncbi.nlm.nih.gov/pubmed/30542595
http://dx.doi.org/10.1039/c8sc02965b

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