Asymmetric Biomimetic Oxidations of Phenols: The Mechanism of the Diastereo- and Enantioselective Synthesis of Thomasidioic Acid

Enantiopure chiral amidic derivatives of sinapic acid were oxidised with hydrogen peroxide using horseradish peroxidase (HRP) as the catalyst to give the aryltetraline dilignol thomasidioic acid. Trans-diastereoselectivity and enantioselectivity in the formation of thomasidioic acid was observed. Co...

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Detalles Bibliográficos
Autores principales: Zoia, Luca, Bruschi, Maurizio, Orlandi, Marco, Tolppa, Eeva-Liisa, Rindone, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2008
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245400/
https://www.ncbi.nlm.nih.gov/pubmed/18259136
http://dx.doi.org/10.3390/molecules13010129

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245400/
https://www.ncbi.nlm.nih.gov/pubmed/18259136
http://dx.doi.org/10.3390/molecules13010129

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