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Asymmetric Biomimetic Oxidations of Phenols: The Mechanism of the Diastereo- and Enantioselective Synthesis of Thomasidioic Acid
Enantiopure chiral amidic derivatives of sinapic acid were oxidised with hydrogen peroxide using horseradish peroxidase (HRP) as the catalyst to give the aryltetraline dilignol thomasidioic acid. Trans-diastereoselectivity and enantioselectivity in the formation of thomasidioic acid was observed. Co...
Autores principales: | Zoia, Luca, Bruschi, Maurizio, Orlandi, Marco, Tolppa, Eeva-Liisa, Rindone, Bruno |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245400/ https://www.ncbi.nlm.nih.gov/pubmed/18259136 http://dx.doi.org/10.3390/molecules13010129 |
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