Unusual Regioselectivity in the Opening of Epoxides by Carboxylic Acid Enediolates

Addition of carboxylic acid dianions appears to be a potential alternative to the use of aluminium enolates for nucleophilic ring opening of epoxides. These conditions require the use of a sub-stoichiometric amount of amine (10% mol) for dianion generation and the previous activation of the epoxide...

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Detalles Bibliográficos
Autores principales: Domingo, Luis R., Gil, Salvador, Parra, Margarita, Segura, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2008
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245471/
https://www.ncbi.nlm.nih.gov/pubmed/18596656
http://dx.doi.org/10.3390/molecules13061303

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245471/
https://www.ncbi.nlm.nih.gov/pubmed/18596656
http://dx.doi.org/10.3390/molecules13061303

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