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Resolving orbital pathways for intermolecular electron transfer

Over 60 years have passed since Taube deduced an orbital-mediated electron transfer mechanism between distinct metal complexes. This concept of an orbital pathway has been thoroughly explored for donor–acceptor pairs bridged by covalently bonded chemical residues, but an analogous pathway has not ye...

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Detalles Bibliográficos
Autores principales: Kellett, Cameron W., Swords, Wesley B., Turlington, Michael D., Meyer, Gerald J., Berlinguette, Curtis P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6249235/
https://www.ncbi.nlm.nih.gov/pubmed/30464202
http://dx.doi.org/10.1038/s41467-018-07263-1