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Conversion of Aryl Iodides into Aryliodine(III) Dichlorides by an Oxidative Halogenation Strategy Using 30% Aqueous Hydrogen Peroxide in Fluorinated Alcohol

Oxidative chlorination with HCl/H(2)O(2) in 1,1,1-trifluoroethanol was used to transform aryl iodides into aryliodine(III) dihalides. In this instance 1,1,1‑trifluoroethanol is not only the reaction medium, but is also an activator of hydrogen peroxide for the oxidation of hydrochloric acid to molec...

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Detalles Bibliográficos
Autores principales: Podgoršek, Ajda, Iskra, Jernej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257259/
https://www.ncbi.nlm.nih.gov/pubmed/20428084
http://dx.doi.org/10.3390/molecules15042857