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New Chiral Phosphoramidite Complexes of Iron as Catalytic Precursors in the Oxidation of Activated Methylene Groups

New phosphoramidite complexes of iron were synthesized and structurally characterized. Reaction of the known chiral phosphoramidites (RO)(2)PNR’(2) (R = binaphthyl, R’ = CH(3), 1a; R = binaphthyl, R’ = benzyl, 1b) with [FeBr(Cp)(CO)(2)] afforded the title compounds [FeBr(Cp)(CO)(1a,b)] (4a,b) in 34...

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Detalles Bibliográficos
Autores principales: Shejwalkar, Pushkar, Rath, Nigam P., Bauer, Eike B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257337/
https://www.ncbi.nlm.nih.gov/pubmed/20428070
http://dx.doi.org/10.3390/molecules15042631