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Double dative bond between divalent carbon(0) and uranium
Dative bonds between p- and d-block atoms are common but species containing a double dative bond, which donate two-electron pairs to the same acceptor, are far less common. The synthesis of complexes between UCl(4) and carbodiphosphoranes (CDP), which formally possess double dative bonds Cl(4)U⇇CDP,...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6258733/ https://www.ncbi.nlm.nih.gov/pubmed/30479324 http://dx.doi.org/10.1038/s41467-018-07377-6 |