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Synthesis of a Highly Luminescent Three-Dimensional Pyrene Dye Based on the Spirobifluorene Skeleton

We have synthesized a highly luminescent (log ε > 5.0, Φ > 0.9) pyrene dye based on a spirobifluorene skeleton [2,2′,7,7′-tetrakis(7-tert-butyl-1-pyrenyl)-9,9′-spirobi[9H-fluorene; 4-PySBF]. The use of spirobifluorene prevents fluorescence quenching by intramolecular energy transfer and/or ele...

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Detalles Bibliográficos
Autores principales: Sumi, Kentaro, Konishi, Gen-ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6259229/
https://www.ncbi.nlm.nih.gov/pubmed/21030911
http://dx.doi.org/10.3390/molecules15117582