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New Chiral P-N Ligands for the Regio- and Stereoselective Pd-Catalyzed Dimerization of Styrene

Two new chiral, enantiomerically pure, hybrid P-N ligands, namely (2R,5S)-2-phenyl-3-(2-pyridyl)-1,3-diaza-2-phosphanicyclo[3,3,0]octan-4-one (1) and (2R,5S)-2-phenyl-3-(2-pyridyl)-1,3-diaza-2-phosphanicyclo[3,3,0]octane (2), have been synthesized starting from L-proline. The two ligands differ in t...

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Detalles Bibliográficos
Autores principales: Fanfoni, Lidia, Meduri, Angelo, Zangrando, Ennio, Castillon, Sergio, Felluga, Fulvia, Milani, Barbara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6259647/
https://www.ncbi.nlm.nih.gov/pubmed/21343886
http://dx.doi.org/10.3390/molecules16021804