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Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes
A series of rare earth complexes of the form Ln(L(R))(3) supported by bidentate ortho-aryloxide–NHC ligands are reported (L(R) = 2-O-3,5-(t)Bu(2)-C(6)H(2)(1-C{N(CH)(2)N(R)})); R = (i)Pr, (t)Bu, Mes; Ln = Ce, Sm, Eu). The cerium complexes cleanly and quantitatively insert carbon dioxide exclusively i...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6262539/ https://www.ncbi.nlm.nih.gov/pubmed/30568765 http://dx.doi.org/10.1039/c8sc03312a |