Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes

A series of rare earth complexes of the form Ln(L(R))(3) supported by bidentate ortho-aryloxide–NHC ligands are reported (L(R) = 2-O-3,5-(t)Bu(2)-C(6)H(2)(1-C{N(CH)(2)N(R)})); R = (i)Pr, (t)Bu, Mes; Ln = Ce, Sm, Eu). The cerium complexes cleanly and quantitatively insert carbon dioxide exclusively i...

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Detalles Bibliográficos
Autores principales: Arnold, Polly L., Kerr, Ryan W. F., Weetman, Catherine, Docherty, Scott R., Rieb, Julia, Cruickshank, Faye L., Wang, Kai, Jandl, Christian, McMullon, Max W., Pöthig, Alexander, Kühn, Fritz E., Smith, Andrew D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6262539/
https://www.ncbi.nlm.nih.gov/pubmed/30568765
http://dx.doi.org/10.1039/c8sc03312a

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