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Catalytic Performance of Ceria Nanorods in Liquid-Phase Oxidations of Hydrocarbons with tert-Butyl Hydroperoxide

The CeO(2) nanorods (CeNR) promote the oxidation of ethylbenzene (PhEt) and cyclohexene with t-BuOOH, at temperatures as low as 55 °C. For both substrates the saturated C-H bonds are preferentially activated over the unsaturated ones. The catalyst seems fairly stable towards leaching phenomena. The...

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Detalles Bibliográficos
Autores principales: Macedo, Andreia G., Fernandes, Sílvia E. M., Valente, Anabela A., Ferreira, Rute. A. S., Carlos, Luís D., Rocha, João
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6263185/
https://www.ncbi.nlm.nih.gov/pubmed/20335943
http://dx.doi.org/10.3390/molecules15020747