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The Influence of t-Butyl and Cyclododecyl Substitution on Ethylene/1-Hexene Copolymerization Using Ansa-Fluorenylamidodimethyltitanium Derivatives

In the present study, copolymerization of ethylene and 1-hexene was conducted with a series of ansa-fluorenylamidodimethyltitanium complexes, including [t-BuNSiMe(2)Flu]TiMe(2) (complex 1), [cyclododecylNSiMe(2)Flu]TiMe(2) (complex 2) and [t-BuNSiMe(2)(2,7-t-Bu(2)Flu)]TiMe(2) (complex 3), activated...

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Detalles Bibliográficos
Autores principales: Kaivalchatchawal, Patcharaporn, Praserthdam, Piyasan, Sogo, Yuuichi, Cai, Zhengguo, Shiono, Takeshi, Jongsomjit, Bunjerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6263282/
http://dx.doi.org/10.3390/molecules16054122