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Probing the Dynamics of Solvation and Structure of the OH(-) Ion in Aqueous Solution from Picosecond Transient Absorption Measurements
The reaction of intracomplex proton transfer (44BPY(-.)...HO-H) → 44BPYH(.) + OH(-) that follows the photoreduction of 4,4’-bipyridine (44BPY) into its anion radical 44BPY(-) in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) is investigated in acetonitrile-water mixtures by using picosecond t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6263321/ https://www.ncbi.nlm.nih.gov/pubmed/20657486 http://dx.doi.org/10.3390/molecules15053366 |