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Ring Cleavage Reactions of Methyl α-D-Allopyranoside Derivatives with Phenylboron Dichloride and Triethylsilane

In the course of our studies on the regioselective carbon-oxygen bond cleavage of the benzylidene acetal group of hexopyranosides with a reducing agent, we found that a combination of a Lewis acid and a reducing agent triggered a ring-opening reaction of the pyranose ring of methyl α-D-allopyranosid...

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Detalles Bibliográficos
Autores principales: Kojima, Masaru, Nakamura, Yutaka, Ito, Yuusuke, Takeuchi, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264258/
https://www.ncbi.nlm.nih.gov/pubmed/22158683
http://dx.doi.org/10.3390/molecules161210303