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Isolation of a Bis-Iodurated Tetra-THF as a Trace Product from the Oxidation of Squalene with RuO(4) and Its Double Ring Expansion to a Novel bis-THF-bis-THP Compound

A novel bis-iodurated polyether compound, based on an unprecedented tetra-THF backbone, has been isolated as a trace by-product of the oxidation of squalene with the catalytic system RuO(2)(cat.)/NaIO(4). The double erythro configuration of the central portion of the molecule furnishes the first ind...

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Detalles Bibliográficos
Autores principales: Piccialli, Vincenzo, Zaccaria, Sabrina, Centore, Roberto, Tuzi, Angela, Borbone, Nicola, Oliviero, Giorgia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264591/
https://www.ncbi.nlm.nih.gov/pubmed/21709619
http://dx.doi.org/10.3390/molecules16075362