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Principles of chemical geometry underlying chiral selectivity in RNA minihelix aminoacylation
The origin of homochirality in L-amino acid in proteins is one of the mysteries of the evolution of life. Experimental studies show that a non-enzymatic aminoacylation reaction of an RNA minihelix has a preference for L-amino acid over D-amino acid. The reaction initiates by approaching of a 3′-oxyg...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Oxford University Press
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6265448/ https://www.ncbi.nlm.nih.gov/pubmed/30321374 http://dx.doi.org/10.1093/nar/gky909 |