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Exploratory Work in the Quaternary System of Ca–Eu–Cd–Sb: Synthesis, Crystal, and Electronic Structures of New Zintl Solid Solutions

Investigation of the quaternary system, Ca–Eu–Cd–Sb, led to a discovery of the new solid solutions, Ca(1−x)Eu(x)Cd(2)Sb(2), with the CaAl(2)Si(2) structure type (x ≈ 0.3–0.9, hP5, P [Formula: see text] m1, a = 4.6632(5)–4.6934(3) Å, c = 7.630(1)–7.7062(7) Å), Ca(2−x)Eu(x)CdSb(2) with the Yb(2)CdSb(2...

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Detalles Bibliográficos
Autores principales: Ovchinnikov, Alexander, Darone, Gregory M., Saparov, Bayrammurad, Bobev, Svilen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6265713/
https://www.ncbi.nlm.nih.gov/pubmed/30384471
http://dx.doi.org/10.3390/ma11112146