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New Methodology for the Synthesis of Thiobarbiturates Mediated by Manganese(III) Acetate
A three step synthesis of various thiobarbiturate derivatives 17–24 was established. The first step is mediated by Mn(OAc)(3), in order to generate a carbon-carbon bond between a terminal alkene and malonate. Derivatives 1–8 were obtained in moderate to good yields under mild conditions. This key st...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268072/ https://www.ncbi.nlm.nih.gov/pubmed/22491680 http://dx.doi.org/10.3390/molecules17044313 |