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(17)O-Dynamic NMR and DFT Investigation of Bis(acyloxy)iodoarenes

Bis(acetoxy)iodobenzene and related acyloxy derivatives of hypervalent I(III) were studied by variable temperature solution-state (17)O-NMR and DFT calculations. The (17)O-NMR spectra reveal a dynamic process that interchanges the oxygen atoms of the acyloxy groups. For the first time, coalescence e...

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Detalles Bibliográficos
Autores principales: Fusaro, Luca, Mocci, Francesca, Luhmer, Michel, Cerioni, Giovanni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268478/
https://www.ncbi.nlm.nih.gov/pubmed/23103535
http://dx.doi.org/10.3390/molecules171112718