H(2)TPP Organocatalysis in Mild and Highly Regioselective Ring Opening of Epoxides to Halo Alcohols by Means of Halogen Elements

We found that elemental iodine and bromine are converted to trihalide nucleophiles (triiodine and tribromide anion, respectively) in the presence of catalytic amounts of meso-tetraphenylporphyrins (H(2)TPP). Therefore a highly regioselective method for the synthesis of β-haloalcohols through direct...

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Detalles Bibliográficos
Autores principales: Torabi, Parviz, Azizian, Javad, Zomorodbakhsh, Shahab
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268510/
https://www.ncbi.nlm.nih.gov/pubmed/22572933
http://dx.doi.org/10.3390/molecules17055508

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268510/
https://www.ncbi.nlm.nih.gov/pubmed/22572933
http://dx.doi.org/10.3390/molecules17055508

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