Tandem RCM–Claisen Rearrangement–[2+2] Cycloaddition of O,O'-(But-2-en-1,4-diyl)-bridged Binaphthols

Attempted RCM of 2,2'-bis(allyloxy)-1,1'-binaphthyl resulted in a Claisen-type rearrangement of a postulated labile dioxacyclodecine proceeding at room temperature and followed by [2+2] cycloaddition. Structures of products were confirmed by X-ray crystallography. A mechanistic rationalisa...

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Detalles Bibliográficos
Autores principales: Abraham, Michael, Reischl, Wolfgang, Kirchner, Karl A., Roller, Alexander, Veiros, Luis F., Widhalm, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268543/
https://www.ncbi.nlm.nih.gov/pubmed/23222901
http://dx.doi.org/10.3390/molecules171214531

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268543/
https://www.ncbi.nlm.nih.gov/pubmed/23222901
http://dx.doi.org/10.3390/molecules171214531

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