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Reactivity of Ruthenium Vinylidene Complexes Containing Indenyl/dppe Ligands and Unsaturated Bonds at Cδ with Trimethylsilyl Azide

This study presents a new reaction of cationic vinylidene complexes with Me(3)SiN(3) (TMSN(3)), which yields N-coordinated nitrile complexes 3. Treatment of a ruthenium acetylide precursor containing indenyl and dppe ligands with a series of organic halides produced the corresponding vinylidene comp...

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Detalles Bibliográficos
Autores principales: Sung, Hui-Ling, Her, Tze-Min, Su, Wen-Hsien, Cheng, Chin-Pao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268553/
https://www.ncbi.nlm.nih.gov/pubmed/22805505
http://dx.doi.org/10.3390/molecules17078533