Cargando…

IBS-Catalyzed Regioselective Oxidation of Phenols to 1,2-Quinones with Oxone(®)

We have developed the first example of hypervalent iodine(V)-catalyzed regioselective oxidation of phenols to o-quinones. Various phenols could be oxidized to the corresponding o-quinones in good to excellent yields using catalytic amounts of sodium salts of 2-iodobenzenesulfonic acids (pre-IBSes) a...

Descripción completa

Detalles Bibliográficos
Autores principales: Uyanik, Muhammet, Mutsuga, Tatsuya, Ishihara, Kazuaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268655/
https://www.ncbi.nlm.nih.gov/pubmed/22810194
http://dx.doi.org/10.3390/molecules17078604