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Synthesis of a 2,2'-Bipyridyl Functionalized Oligovinylene-Phenylene Using Heck and Horner-Wadsworth-Emmons Reactions and X-ray Crystal Structure of E-(4-(4-Bromostyryl)phenyl)(methyl)sulfane

The synthesis of a new 2,2'-bipyridyl functionalized oligovinylenephenylene (OVP-5) containing a methyl protected thiol using Heck coupling and the Horner-Wadsworth-Emmons reaction and is described. A key step involving a diisopropylcarbodiimide promoted dehydration of a stable β-hydroxyphospho...

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Detalles Bibliográficos
Autores principales: Karácsony, Orsolya, Deschamps, Jeffrey R., Trammell, Scott A., Nita, Rafaela, Knight, D. Andrew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268687/
https://www.ncbi.nlm.nih.gov/pubmed/22628044
http://dx.doi.org/10.3390/molecules17055724