Hybridization vs. Bond Stretching Isomerism in Ru(II) Cyclometalated Complexes of 2-Phenylpyridine

The phenomenon of formation of two isomers, yellow and orange, of the cyclometalated Ru(II) complex, [Ru(o-C(6)H(4)-py)(MeCN)(4)](+), was investigated by EELS spectroscopy and theoretical calculations. Both forms show very similar structures and spectroscopic properties, but slight differences in X-...

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Detalles Bibliográficos
Autores principales: Molina, Bertha, Alexandrova, Larissa, LeLagadec, Ronan, Sansores, Luis E., Rios-Jara, David, Espinosa-Magaña, Francisco, Salcedo, Roberto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268727/
https://www.ncbi.nlm.nih.gov/pubmed/22193212
http://dx.doi.org/10.3390/molecules17010034

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268727/
https://www.ncbi.nlm.nih.gov/pubmed/22193212
http://dx.doi.org/10.3390/molecules17010034

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