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Reaction of Iodonium Ylides of 1,3-Dicarbonyl Compounds with HF Reagents

Reaction of dibenzoylmethane with (diacetoxyiodo)benzene in the presence of KOH in MeCN quantitatively gave the corresponding iodonium ylide, which was treated with a HF reagent to afford the corresponding 2-fluorinated dibenzoylmethane in 14–50% yields. The similar reaction of the iodonium ylides o...

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Detalles Bibliográficos
Autores principales: Gondo, Keisuke, Kitamura, Tsugio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268728/
https://www.ncbi.nlm.nih.gov/pubmed/22728358
http://dx.doi.org/10.3390/molecules17066625