Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis

One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.

Detalles Bibliográficos
Autores principales: Sono, Masakazu, Ise, Natsuko, Shoji, Tsutomu, Tori, Motoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268971/
https://www.ncbi.nlm.nih.gov/pubmed/22976471
http://dx.doi.org/10.3390/molecules170911079

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268971/
https://www.ncbi.nlm.nih.gov/pubmed/22976471
http://dx.doi.org/10.3390/molecules170911079

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