Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis

One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.

Detalles Bibliográficos
Autores principales: Sono, Masakazu, Ise, Natsuko, Shoji, Tsutomu, Tori, Motoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268971/
https://www.ncbi.nlm.nih.gov/pubmed/22976471
http://dx.doi.org/10.3390/molecules170911079
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author Sono, Masakazu
Ise, Natsuko
Shoji, Tsutomu
Tori, Motoo
author_facet Sono, Masakazu
Ise, Natsuko
Shoji, Tsutomu
Tori, Motoo
author_sort Sono, Masakazu
collection PubMed
description One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
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spelling pubmed-62689712018-12-12 Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis Sono, Masakazu Ise, Natsuko Shoji, Tsutomu Tori, Motoo Molecules Article One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions. MDPI 2012-09-13 /pmc/articles/PMC6268971/ /pubmed/22976471 http://dx.doi.org/10.3390/molecules170911079 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Sono, Masakazu
Ise, Natsuko
Shoji, Tsutomu
Tori, Motoo
Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis
title Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis
title_full Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis
title_fullStr Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis
title_full_unstemmed Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis
title_short Cyclizations Producing Hydrindanones with Two Methyl Groups at the Juncture Positions Mediated by Samarium Diiodide and Electrolysis
title_sort cyclizations producing hydrindanones with two methyl groups at the juncture positions mediated by samarium diiodide and electrolysis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268971/
https://www.ncbi.nlm.nih.gov/pubmed/22976471
http://dx.doi.org/10.3390/molecules170911079
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