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Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature

Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

Detalles Bibliográficos
Autores principales: Kuo, Chun-Wei, Hsieh, Min-Tsang, Gao, Shijay, Shao, Yi-Ming, Yao, Ching-Fa, Shia, Kak-Shan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268980/
https://www.ncbi.nlm.nih.gov/pubmed/23169264
http://dx.doi.org/10.3390/molecules171113662