Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature

Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

Detalles Bibliográficos
Autores principales: Kuo, Chun-Wei, Hsieh, Min-Tsang, Gao, Shijay, Shao, Yi-Ming, Yao, Ching-Fa, Shia, Kak-Shan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268980/
https://www.ncbi.nlm.nih.gov/pubmed/23169264
http://dx.doi.org/10.3390/molecules171113662
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author Kuo, Chun-Wei
Hsieh, Min-Tsang
Gao, Shijay
Shao, Yi-Ming
Yao, Ching-Fa
Shia, Kak-Shan
author_facet Kuo, Chun-Wei
Hsieh, Min-Tsang
Gao, Shijay
Shao, Yi-Ming
Yao, Ching-Fa
Shia, Kak-Shan
author_sort Kuo, Chun-Wei
collection PubMed
description Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
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spelling pubmed-62689802018-12-13 Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature Kuo, Chun-Wei Hsieh, Min-Tsang Gao, Shijay Shao, Yi-Ming Yao, Ching-Fa Shia, Kak-Shan Molecules Article Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields. MDPI 2012-11-20 /pmc/articles/PMC6268980/ /pubmed/23169264 http://dx.doi.org/10.3390/molecules171113662 Text en © 2012 by the authors. licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Kuo, Chun-Wei
Hsieh, Min-Tsang
Gao, Shijay
Shao, Yi-Ming
Yao, Ching-Fa
Shia, Kak-Shan
Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature
title Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature
title_full Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature
title_fullStr Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature
title_full_unstemmed Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature
title_short Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature
title_sort beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268980/
https://www.ncbi.nlm.nih.gov/pubmed/23169264
http://dx.doi.org/10.3390/molecules171113662
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