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General Intermediates for the Synthesis of 6-C-Alkylated DMDP-Related Natural Products

Protected L-homoDMDP en-8 and its C-6 epimer en-7 were prepared through two different pathways starting from the vinylpyrrolidine en-9. Based on the NMR and X-ray analysis, the stereochemistry of homoDMDP at C-6 was confirmed to be consistent with reported data. Compounds en-7 and en-8 are general i...

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Detalles Bibliográficos
Autores principales: Huang, Mu-Hua, Li, Yi-Xian, Jia, Yue-Mei, Yu, Chu-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269708/
https://www.ncbi.nlm.nih.gov/pubmed/23749160
http://dx.doi.org/10.3390/molecules18066723