An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones

A new bidentate phosphoramidite (N-Me-BIPAM) based on Shibasaki’s N-linked BINOL was synthesized. This ligand appears to be highly effective for rhodium-catalyzed asymmetric conjugated addition of arylboronic acids to α,β-unsaturated enones. The reaction of ortho-substituted arylboronic acid with ac...

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Detalles Bibliográficos
Autores principales: Yamamoto, Yasunori, Kurihara, Kazunori, Takahashi, Yoshinori, Miyaura, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269836/
https://www.ncbi.nlm.nih.gov/pubmed/23344185
http://dx.doi.org/10.3390/molecules18010014

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269836/
https://www.ncbi.nlm.nih.gov/pubmed/23344185
http://dx.doi.org/10.3390/molecules18010014

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