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Manganese(III) Acetate-mediated Oxidative Cyclization of α-Methylstyrene and trans-Stilbene with β-Ketosulfones

A convenient microwave irradiation protocol was utilized for the synthesis of β-ketosulfones 1–5 in good yields. These sulfones reacted with alkenes through a radical oxidative cyclization mediated by Mn(OAc)(3). Dihydrofurans 6–10 were obtained in moderate to good yields starting from 1,1-disubstit...

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Detalles Bibliográficos
Autores principales: Bouhlel, Ahlem, Curti, Christophe, Tabelé, Clémence, Vanelle, Patrice
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269865/
https://www.ncbi.nlm.nih.gov/pubmed/23579996
http://dx.doi.org/10.3390/molecules18044293