Perfluoroalkanesulfonamide Organocatalysts for Asymmetric Conjugate Additions of Branched Aldehydes to Vinyl Sulfones

Asymmetric conjugate additions of branched aldehydes to vinyl sulfones promoted by sulfonamide organocatalyst 6 or 7 have been developed, allowing facile synthesis of the corresponding adducts with all-carbon quaternary stereocenters in excellent yields with up to 95% ee.

Detalles Bibliográficos
Autores principales: Nakashima, Kosuke, Murahashi, Miho, Yuasa, Hiroki, Ina, Mariko, Tada, Norihiro, Itoh, Akichika, Hirashima, Shin-ichi, Koseki, Yuji, Miura, Tsuyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269931/
https://www.ncbi.nlm.nih.gov/pubmed/24287989
http://dx.doi.org/10.3390/molecules181214529

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269931/
https://www.ncbi.nlm.nih.gov/pubmed/24287989
http://dx.doi.org/10.3390/molecules181214529

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