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Perfluoroalkanesulfonamide Organocatalysts for Asymmetric Conjugate Additions of Branched Aldehydes to Vinyl Sulfones

Asymmetric conjugate additions of branched aldehydes to vinyl sulfones promoted by sulfonamide organocatalyst 6 or 7 have been developed, allowing facile synthesis of the corresponding adducts with all-carbon quaternary stereocenters in excellent yields with up to 95% ee.

Detalles Bibliográficos
Autores principales:	Nakashima, Kosuke, Murahashi, Miho, Yuasa, Hiroki, Ina, Mariko, Tada, Norihiro, Itoh, Akichika, Hirashima, Shin-ichi, Koseki, Yuji, Miura, Tsuyoshi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2013
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269931/ https://www.ncbi.nlm.nih.gov/pubmed/24287989 http://dx.doi.org/10.3390/molecules181214529

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