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Highly Enantioselective Addition of Phenylethynylzinc to Aldehydes Catalyzed by Chiral Cyclopropane-Based Amino Alcohols

The enantioselective addition of phenylethynylzinc to aldehydes catalyzed by a series of cyclopropane-based amino alcohol ligands 7 was investigated. The reactions afforded chiral propargylic alcohols in high yields (up to 96%) and with excellent enantioselectivities (up to 98% ee) under mild condit...

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Detalles Bibliográficos
Autores principales:	Zheng, Bing, Li, Zhiyuan, Liu, Feipeng, Wu, Yanhua, Shen, Junjian, Bian, Qinghua, Hou, Shicong, Wang, Ming
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2013
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270052/ https://www.ncbi.nlm.nih.gov/pubmed/24335619 http://dx.doi.org/10.3390/molecules181215422

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