Synthesis and NMR-Study of 1-Trimethylsilyl Substituted Silole Anion [Ph(4)C(4)Si(SiMe(3))](−)•[Li](+) and 3-Silolenide 2,5-carbodianions {[Ph(4)C(4)Si(n-Bu)(2)](−2)•2[Li](+), [Ph(4)C(4)Si(t-Bu)(2)](−2)•2[Li](+)} via Silole Dianion [Ph(4)C(4)Si](−2)•2[Li](+)

1-Trimethylsilyl, 1-R (R = Me, Et, i-Bu)-2,3,4,5-tetraphenyl-1-silacyclopentadiene [Ph(4)C(4)Si(SiMe(3))R] are synthesized from the reaction of 1-trimethylsilyl,1-lithio-2,3,4,5-tetraphenyl-1-silacyclopentadienide anion [Ph(4)C(4)SiMe(3)](−)•[Li](+) (3) with methyl iodide, ethyl iodide, and i-butyl...

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Detalles Bibliográficos
Autor principal: Hong, Jang-Hwan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270468/
https://www.ncbi.nlm.nih.gov/pubmed/23999728
http://dx.doi.org/10.3390/molecules180910568

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270468/
https://www.ncbi.nlm.nih.gov/pubmed/23999728
http://dx.doi.org/10.3390/molecules180910568

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