Modes of Neighbouring Group Participation by the Methyl Selenyl Substituent in β-Methylselenylmethyl-substituted 1-Phenylethyl Carbenium Ions

Selenium substituents which are disposed β to an electron deficient centre, such as a carbocation p-orbital, or the π* orbital of an electron deficient p-system, interact in a stabilising way by a combination of C-Se hyperconjugation (σ(Se-C)–π* interaction), and a through-space homoconjugative n(Se...

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Detalles Bibliográficos
Autores principales: Harris, Benjamin L., White, Jonathan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270508/
https://www.ncbi.nlm.nih.gov/pubmed/24071979
http://dx.doi.org/10.3390/molecules181011705

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270508/
https://www.ncbi.nlm.nih.gov/pubmed/24071979
http://dx.doi.org/10.3390/molecules181011705

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