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Photochemical Aryl Radical Cyclizations to Give (E)-3-Ylideneoxindoles

(E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts.

Detalles Bibliográficos
Autores principales: Gurry, Michael, Allart-Simon, Ingrid, McArdle, Patrick, Gérard, Stéphane, Sapi, Janos, Aldabbagh, Fawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270804/
https://www.ncbi.nlm.nih.gov/pubmed/25271428
http://dx.doi.org/10.3390/molecules191015891